Hey there Chigady,
I reckon that you should stick to backpacking. Volunteering programmes are, for the most part, fairly expensive especially if you are only able to go for a couple of weeks. If you have a smallish budget then I reckon that you would get more out of your trip if you are backpacking.
I'm going to Ghana next year - volunteering for three months and then cycling around the southern part of the country for two. For the backpacking/cycling part I'm planning on being able to live on $20 a day. On top of that you obviously have flights (hopefully around the £400 mark), visa (£30 for single entry) and vaccinations (I think the three you have to get done privately are Yellow Fever: £47, Meningitis £45 and Rabies: £135).
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